甲苯
光催化
离解(化学)
卤化物
化学
光化学
载流子
带隙
密度泛函理论
钙钛矿(结构)
催化作用
无机化学
材料科学
物理化学
有机化学
计算化学
光电子学
作者
Zhangjun Bai,Xi-Ping Tan,Lang Chen,Biao Hu,Yuxuan Tan,Yu Mao,Sheng Shen,Jun‐Kang Guo,Chak‐Tong Au,Zhiwu Liang,Shuang-Feng Yin
标识
DOI:10.1016/j.ces.2021.116983
摘要
Inert C–H bonds activation at room temperature has been regarded as the control step in photocatalytic generation of valuable products from hydrocarbons. Herein, lead-free perovskite Cs3Bi1.8Sb0.2Br9 nanosheets with a proper amount of Sb in Cs3Bi2Br9 not only improves optical absorption due to anomalous band gap behavior, but also promotes the generation of holes (h+). The convergence of h+ on the surface of Cs3Bi1.8Sb0.2Br9 is crucial for the dissociation of toluene C(sp3)–H bond, which was proved by the density functional theory calculation and isotopic labelling results. The excellent activity in photocatalytic selective oxidation of toluene with a conversion rate of 5.83 mmol g−1h−1 under visible light is the highest ever achieved. This work sheds light on the modification of halide perovskites through the regulation of B-site cations for photocatalytic applications.
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