材料科学
插层(化学)
离子
碱金属
分子
萃取(化学)
支柱
化学工程
复合材料
纳米技术
无机化学
结构工程
量子力学
物理
工程类
色谱法
有机化学
化学
作者
Mao‐Cheng Liu,Bin‐Mei Zhang,Yushan Zhang,Bing‐Ni Gu,Chen‐Yang Tian,Dong‐Ting Zhang,Yaqin Wang,Bei Zhao,Yuanyi Wang,Mingjin Liu,Yi‐Jen Yu,Kun Zhao,Ling‐Bin Kong,Yu‐Lun Chueh
标识
DOI:10.1016/j.mtener.2021.100832
摘要
An ion insertion type in two-dimensional (2D) materials has attracted extensive attention making 2D materials as promising energy storage materials. However, the interlayer spacing plays a key role in the design of 2D materials with fast ions de-intercalation dynamics and high-rate capability. Here, an unprecedented and convenient organic molecular welding approach was proposed to controllably tune different interlayer spacings in Ti3C2 MXene layers, resulting in pillar and strain-xDA-Ti3C2 structures by a dehydration condensation reaction between diacid molecules (HOOC(CH2)nCOOH) and -NH2 functionalized Ti3C2 layers. The xDA molecules can not only tighten the adjacent layers acting as ropes during the ion insertion process but also pillar the adjacent layers when ion extraction process was used to stabilize the Ti3C2 structure by suppressing the volume change. Furthermore, the interlayer spacing of xDA-Ti3C2 can be controllably tuned from 1.03 to 1.45 nm by choosing xDA with different lengths and controlled interlayer spacings of 1.35 and 1.38 nm can be achieved for the best rate capability of insertion/extraction processes with the superior diffusion coefficient of 4.6 × 10−7/2.8 × 10−8 cm2/s in Li+/Na+ batteries, respectively.
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