Multifunctional Role of MoS2 in Preparation of Composite Hydrogels: Radical Initiation and Cross-Linking

This paper describes the multifunctional effect of molybdenum disulfide (MoS₂) that enables the rapid and accessible preparation of nanocomposite hydrogels via a bottom-up design. The MoS₂ nanoplatelet forms radical species through a redox reaction with persulfate under aqueous conditions while initiating the polymerization of acrylic monomers and providing noncovalent cross-linking points without requiring external stimuli or extra cross-linkers, leading to the formation of hydrogels that are in situ embedded with inorganic flakes. Furthermore, the addition of MoS₂ could induce more rigid and elastic networks compared to those in control hydrogels using a typical cross-linker at the same level; for example, 0.08 wt % MoS₂ resulted in a composite hydrogel of which the elastic modulus was 2.5 times greater than that from a hydrogel using N,N'-methylenebis(acrylamide) as the showing phase transition during polymerization. The composite hydrogels are self-healable, taking advantage of reversible physical cross-links. Thus, two cut hydrogel strips could be readily rejoined by heating at 70 °C, and the resulting whole strip showed mechanical strength similar to that of the pristine sample before it was cut. This synthetic approach would give way to the modular design of MoS₂-containing composite hydrogels.