炭黑
微型多孔材料
材料科学
质子交换膜燃料电池
化学工程
接触角
复合材料
介电谱
碳纤维
电化学
天然橡胶
燃料电池
化学
复合数
电极
物理化学
工程类
作者
Guangyi Lin,Shouyi Liu,Boquan Yu,Hong Wang,Kaiben Yu,Yafei Hu
摘要
Abstract The newly prepared gas diffusion layer (GDL) was studied in this article. The new GDL mainly includes a carbon paper layer and two microporous layers (MPLs) on the same side of carbon paper. The two MPLs were fabricated by using conductive carbon blacks of two different carbon morphology, Vulcan XC‐72, and acetylene black carbon, respectively. From the results of the water contact angle and conductivity, it was found that the GDL prepared by spraying has not only good hydrophobicity but also low resistivity. Polarization curve and electrochemical impedance spectroscopy indicated that the spraying sequence of two different carbon black pastes seriously affects the fuel cell performance, and the mercury intrusion test proved that the change in the fuel cell performance is due to the change in the pore‐size distribution of the newly prepared GDL. By comparing with commercial GDL29BC, the GDL first sprayed with a layer of acetylene black carbon and then a layer of Vulcan XC‐72 has more pore size of 7–20 μm and 20–100 μm to improve the water and gas management capability of proton exchange membrane fuel cells. When the humidity is 60%, the maximum power density is increased by 25%, and when the humidity is 100%, it is increased by 12%.
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