材料科学
涂层
阴极
图层(电子)
降级(电信)
化学工程
锂(药物)
离子
表面改性
复合材料
化学
电子工程
有机化学
内分泌学
物理化学
工程类
医学
作者
Hongqiang Wang,Youqi Chu,Qichang Pan,Guangchang Yang,Anjie Lai,Zhiheng Liu,Fenghua Zheng,Sijiang Hu,Youguo Huang,Qingyu Li
标识
DOI:10.1016/j.electacta.2020.137476
摘要
Abstract Nickel-rich are considered as promising cathodes for high energy density of lithium-ion batteries (LIBs) due to their high capacity and low cost. However, the rapid capacity fading caused by interface instability and structure degradation during the charge/discharge process which lead to poor cycling performance, and seriously limited their practical application in LIBs. Herein, we report a coating modification strategy for synthesis of LiAlO2/LiF&AlF3 hybrid coating layer on LiNi0.6Co0.2Mn0.2O2 surface. In constructed this hybrid layer, the LiAlO2 with high ionic conductor could can tightly immobilize on NCM surface, and the LiF&AlF3 layer can function as an isolated layer to suppress the attack by HF. Therefore, combined with the advantages of LiAlO2/LiF&AlF3 hybrid coating layer, the structural degradation and intergranular cracks can be effective mitigated during the long-term cycling process. As a consequence, the hybrid layer modified LiNi0.6Co0.2Mn0.2O2 materials exhibit a discharge capacity of 166.8 mAh g−1 with capacity retention of 74.5% at 5 C after 300 cycles. Moreover, the rate performance was also enhanced, and deliver a discharge capacity of 155 mAh g−1 even at 10 C.
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