Antifouling Nanofiltration Membrane Fabrication via Surface Assembling Light-Responsive and Regenerable Functional Layer

Membrane fouling, caused by aggregation of organics and microorganisms from filtrate on the membrane surface, seriously reduces the service life of a nanofiltration (NF) membrane. Developing facile and renewable antifouling modification methods without sacrificing separation properties of the membrane remain an imperative requirement. Herein, a thin-film composite (TFC) NF membrane with a light-responsive and regenerable functional layer (P-TFC) was fabricated via host-guest interactions between the azobenzene (guest) labeled functional polymers and the β-cyclodextrin (host) bonded membrane surface (H-TFC). The P-TFC-3 not only showed outstanding antifouling ability and high flux recovery ratio (FRR > 90% at the fourth antiadhesive test) but also exhibited enhanced water permeability (17.9 L m^-2 h^-1 bar^-1) and high selectivity (α_MgSO4^NaCl = 33.4 and fast antibiotics enrichment capacity) compared with the pristine membrane. Furthermore, when the functional layer was contaminated, it can be removed by ultraviolet light irradiation and a new functional layer can be rebuilt by adding fresh azobenzene labeled functional polymers. After several regeneration processes, the membranes still showed constant separation properties and high flux recovery ability (FRR > 90%). This work proposes an easy-to-assemble and regenerable surface modification strategy to endow TFC NF membranes with excellent fouling resistance and sustainable utilization ability while maintaining high separation properties.