Recent advances in the cross-coupling reactions of organoboron derivatives with organic electrophiles, 1995–1998

化学 铃木反应 偶联反应 电泳剂 试剂 组合化学 催化作用 联轴节(管道) 有机硼化合物 有机化学 计算化学 机械工程 工程类
作者
Akira Suzuki
出处
期刊:Journal of Organometallic Chemistry [Elsevier BV]
卷期号:576 (1-2): 147-168 被引量:2779
标识
DOI:10.1016/s0022-328x(98)01055-9
摘要

The palladium-catalyzed cross-coupling reaction between organoboron compounds and organic halides or triflates provides a powerful and general methodology for the formation of carbon–carbon bonds. Recently, this reaction has been called the Suzuki coupling, Suzuki reaction, or Suzuki–Miyaura coupling, although we never referred to it as such previously. In this review, this name will be used with hesitation, simply in order to express the coupling reaction. The availability of the reagents and the mild reaction conditions all contribute to the versatility of this reaction. The coupling reaction offers several additional advantages, such as being largely unaffected by the presence of water, tolerating a broad range of functional groups, and proceeding generally regio- and stereoselectively. Moreover, the inorganic by-product of the reaction is non-toxic and easily removed from the reaction mixture thereby making the Suzuki coupling suitable not only for laboratories but also for industrial processes. We published previously a comprehensive review of the reaction (see N. Miyaura, A. Suzuki, Chem. Rev. 95 (1995) 2457 and A. Suzuki, in: F. Diederich, P.J. Stang, (Eds.), Metal-Catalyzed Cross-coupling Reactions, VCH, Weinheim, 1998, pp. 49–97), which covered mainly the references until the end of 1994. Thereafter, a large number of papers related to the coupling reaction have been reported. Consequently, such new results presented from 1995 to May 1998 are summarized in this review.
最长约 10秒,即可获得该文献文件

科研通智能强力驱动
Strongly Powered by AbleSci AI
更新
PDF的下载单位、IP信息已删除 (2025-6-4)

科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
华仔应助一蓑烟雨任平生采纳,获得10
1秒前
NexusExplorer应助Hesse采纳,获得10
1秒前
可爱的函函应助吴家辉采纳,获得10
1秒前
苏苏发布了新的文献求助10
2秒前
2秒前
2秒前
5秒前
6秒前
万能图书馆应助墨客采纳,获得10
6秒前
linna发布了新的文献求助10
6秒前
6秒前
lllllllll发布了新的文献求助10
6秒前
7秒前
景穆完成签到,获得积分10
7秒前
小太阳发布了新的文献求助10
8秒前
9秒前
YYONE完成签到,获得积分10
9秒前
11秒前
可爱的函函应助allrubbish采纳,获得10
11秒前
02完成签到,获得积分10
11秒前
ZMY发布了新的文献求助10
11秒前
可靠觅珍应助C.Cat采纳,获得50
12秒前
wanci应助难过千易采纳,获得10
14秒前
汉堡包应助Aaron采纳,获得10
14秒前
华仔应助YYONE采纳,获得10
14秒前
1111完成签到,获得积分10
15秒前
李健应助rain采纳,获得30
16秒前
16秒前
潮潮发布了新的文献求助10
17秒前
17秒前
SCI发布了新的文献求助10
17秒前
大宝完成签到 ,获得积分20
20秒前
量子星尘发布了新的文献求助10
21秒前
louis136116发布了新的文献求助10
22秒前
23秒前
23秒前
潮潮完成签到,获得积分10
24秒前
CipherSage应助箱箱采纳,获得10
24秒前
24秒前
linna完成签到,获得积分10
25秒前
高分求助中
Picture Books with Same-sex Parented Families: Unintentional Censorship 700
ACSM’s Guidelines for Exercise Testing and Prescription, 12th edition 500
Nucleophilic substitution in azasydnone-modified dinitroanisoles 500
不知道标题是什么 500
Indomethacinのヒトにおける経皮吸収 400
Phylogenetic study of the order Polydesmida (Myriapoda: Diplopoda) 370
Effective Learning and Mental Wellbeing 300
热门求助领域 (近24小时)
化学 材料科学 医学 生物 工程类 有机化学 生物化学 物理 内科学 纳米技术 计算机科学 化学工程 复合材料 遗传学 基因 物理化学 催化作用 冶金 细胞生物学 免疫学
热门帖子
关注 科研通微信公众号,转发送积分 3975339
求助须知:如何正确求助?哪些是违规求助? 3519670
关于积分的说明 11199199
捐赠科研通 3256002
什么是DOI,文献DOI怎么找? 1798043
邀请新用户注册赠送积分活动 877386
科研通“疑难数据库(出版商)”最低求助积分说明 806305