材料科学
石墨烯
阳极
共轭体系
聚合物
法拉第效率
分散性
纳米技术
化学工程
离子
锂(药物)
电极
高分子化学
有机化学
复合材料
物理化学
内分泌学
化学
工程类
医学
作者
Zong‐Qiong Lin,Jian Xie,Bowei Zhang,Jiewei Li,Jiena Weng,Rong‐Bin Song,Xiao Huang,Hao Zhang,Hai Li,Ye Liu,Zhichuan J. Xu,Wei Huang,Qichun Zhang
出处
期刊:Nano Energy
[Elsevier]
日期:2017-11-01
卷期号:41: 117-127
被引量:170
标识
DOI:10.1016/j.nanoen.2017.08.038
摘要
Preparing well-defined single-layer two-dimensional (2D) holey conjugated polymers (HCP) is very challenging. Here, we report a bottom-up method to produce free-standing single-layer nitrogen-rich graphene-like holey conjugated polymers (NG-HCP) nanosheets through solution-process. The as-prepared 2D NG-HCP sheet possesses a thickness of 1.0 ± 0.2 nm and consists of graphene-like subunits as well as homogeneous hexagonal micropores (ca. 11.65 Å). The synergistic effect of high porosity, heteroatomic doping and good dispersity of NG-HCP nanosheets make them suitable as excellent anode materials for Li-ion batteries (LIBs), leading to an extremely high reversible capacity of 1320 mAh g−1 (at 20 mA g−1), a good rate performance, and an excellent cycle life with an approximate 100% Coulombic efficiency for more than 600 cycles. Our findings would open new opportunities to develop state-of-the-art free-standing 2D-HCP materials for low-cost and high performance energy storage as well as optoelectronic devices.
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