Effects of temperature on the emission of particulate matter, polycyclic aromatic hydrocarbons, and polybrominated diphenyl ethers from the thermal treatment of printed wiring boards

The effects of temperature on the emission of pollutants during the thermal treatment of electronic waste have rarely been investigated. The emission of particulate matter (PM), polycyclic aromatic hydrocarbons (PAHs), and polybrominated diphenyl ethers (PBDEs) from the thermal treatment of printed wiring boards was investigated over a temperature range of 320-600 °C. The emission factors (EFs) were determined to be within 1.6-7.6 g/kg, 2.23-11.9 μg/g, and 0.9-5.5 μg/g, respectively. High temperatures increased the formation of PAHs and CO, but decreased the emission of PBDEs, PM, and organic carbon. A temperature of 480 °C was determined to be optimal. Low-molecular-weight components were the dominant PAH species. The compositional profiles of PBDEs were clearly observed to vary with the temperature. Small particles (< 2.1 μm) that were more affected by temperature were dominant in PM, particle-bound PAHs, and PBDEs at all temperatures. High temperature increased the EFs of gaseous PAHs but had no remarkable effect on those of particulate PAHs. The freshly emitted PAHs primarily existed in the particulate phase at low temperatures, while the gaseous phase PAHs became prevailing at ≥ 520 °C. The particulate PBDEs were more susceptible to temperature and overwhelmingly dominant over the entire temperature range considered.