材料科学
阳极
电解质
电极
锂(药物)
激光烧蚀
激光器
光电子学
石墨
储能
复合材料
光学
功率(物理)
内分泌学
物理化学
化学
物理
医学
量子力学
作者
Jan Bernd Habedank,J. G. Endres,Patrick Schmitz,Michael F. Zaeh,H. Huber
出处
期刊:Journal of Laser Applications
[Laser Institute of America]
日期:2018-06-14
卷期号:30 (3)
被引量:66
摘要
Lithium-ion batteries are widely used as energy storage devices due to their high energy density and versatile applicability. Key components of lithium-ion batteries are electrically isolated electrodes and a liquid electrolyte solution which enables ion transport between the electrodes. Laser structuring of electrodes is a promising approach to enhance the high-current capability of lithium-ion batteries by reducing cell internal resistances, as a larger contact area of the active material with the electrolyte solution is created. In the work described here, lithium-ion battery anodes were structured by locally ablating small fractions of the coating using femtosecond laser pulses with infrared wavelengths. A study on ablation characteristics depending on different process parameters such as laser fluence and repetition rate was performed. Special focus was on the ablation efficiency, enabling an optimized process design. The influence of the electrode composition was taken into account by studying the ablation behavior at a varying binder content. Evenly distributed micro holes were chosen in order to keep active material removal at a minimum. To evaluate the effect of structured graphite anodes on the electrochemical properties of lithium-ion batteries, test cells were manufactured and galvanostatically cycled at different current rates. Results show improvements in high-current performance which is expressed by an increased discharge capacity yield.
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