磷酸盐
吸附
化学
生物炭
稻草
浸出(土壤学)
纳米复合材料
化学工程
解吸
镧
核化学
X射线光电子能谱
无机化学
有机化学
热解
土壤水分
土壤科学
工程类
环境科学
作者
Hui Qiu,Liang Chen,Jianghua Yu,Qingrui Zhang,Mingxia Song,Fenghua Chen
标识
DOI:10.1016/j.cej.2017.01.043
摘要
Enhanced removal of phosphate by biomass-supported adsorbents is an effective and economic method to prevent the accelerated eutrophication in water body. A new nanocomposite Ws-N-La is fabricated for efficient phosphate removal by immobilizing “rod-like” nano-sized La(III) (hydr)oxides within a quaternary-aminated wheat straw (Ws-N). It exhibits higher adsorption capacity towards phosphate than the commercial IRA-900 or HFO-201 even at higher competing anions levels. The pH result indicated that the Ws-N-La would effectively sequestrate phosphate over a wide pH range between 3.0 and 7.0 without significant La(III) leaching. Ten cycles of adsorption-desorption experiments reveals that no significant capacity loss is observed, indicating excellent stability and repeated use property than any other La(III)-based adsorbents. The results of TEM, XRD and XPS analysis demonstrated that the formation of “needle-like” lanthanum phosphate nanoparticle is the dominant pathway for the specific adsorption of phosphate by nano-La(III) (hydr)oxides. All the results suggested that the biomass-supported nano-composite Ws-N-La can serve as a promising adsorbent for preferable phosphate removal in realistic application.
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