材料科学
氮氧化物
无机化学
X射线光电子能谱
锰
氨
氧化还原
吸附
选择性
作者
Shihui Li,Bichun Huang,Changming Yu
标识
DOI:10.1016/j.catcom.2017.04.046
摘要
A CeO2-MnOx catalyst with a core-shell structure was prepared by a chemical deposition method and tested towards the low-temperature selective catalytic reduction of NO by NH3. The catalyst with a molar ratio of CeO2/MnOx = 0.6, exhibited a relatively high conversion values of NO in the 110–220 °C range and good resistance to SO2 and H2O at the space velocity of 40,000 h− 1. The excellent catalytic performance could be attributed to the presence of high crystalline α-MnO2, as well as high concentrations of Mn4 + and Ce3 +. Notably, CeO2-MnOx catalyst showed relatively good resistance to SO2 due to its core-shell structure.
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