化学
反应性(心理学)
金属
分子
单层
星团(航天器)
化学反应
极地的
气相
化学物理
计算化学
纳米技术
有机化学
医学
物理
病理
天文
生物化学
材料科学
程序设计语言
替代医学
计算机科学
作者
Zhixun Luo,A. W. Castleman,Shiv N. Khanna
出处
期刊:Chemical Reviews
[American Chemical Society]
日期:2016-11-28
卷期号:116 (23): 14456-14492
被引量:392
标识
DOI:10.1021/acs.chemrev.6b00230
摘要
We summarize here the research advances on the reactivity of metal clusters. After a simple introduction of apparatuses used for gas-phase cluster reactions, we focus on the reactivity of metal clusters with various polar and nonpolar molecules in the gas phase and illustrate how elementary reactions of metal clusters proceed one-step at a time under a combination of geometric and electronic reorganization. The topics discussed in this study include chemical adsorption, addition reaction, cleavage of chemical bonds, etching effect, spin effect, the harpoon mechanism, and the complementary active sites (CAS) mechanism, among others. Insights into the reactivity of metal clusters not only facilitate a better understanding of the fundamentals in condensed-phase chemistry but also provide a way to dissect the stability and reactivity of monolayer-protected clusters synthesized via wet chemistry.
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