Large scale fabrication of recyclable and multifunctional sandwich-structured electromagnetic interference shielding films based on waste Nylon-6 silk

Modern wearable electronics are being miniaturized with high integration and frequency, leading to excess electromagnetic radiation, heat storage, and fire risk. Besides overcoming these safety issues, realizing large-scale, low-cost and recyclable preparation of multifunctional films are urgently required for practical applications of electromagnetic interference (EMI) shielding. Herein, sandwich-structured films have been prepared using commercial nylon mesh (CNM) with a waste nylon-6 silk/ammonium polyphosphate (PA6/APP) porous flame-retardant outer layer and inner conductive ultra-long silver nanowires (AgNWs) network. Only 0.2 mg/cm2 of the conductive inner layer endows the films with excellent EMI shielding performance (53.7 dB), thermal diffusivity (5.206 ± 0.087 mm2/s) and antibacterial properties. In addition, the unique honeycomb structure of the PA6/APP outer layer produced during water bath treatment endows the films with superior printability. And such modified porous outer layer of the sandwich-structured films realizes a V0 rating during the UL-94 test. Even when these films are scrapped, they can still be recycled and reused. In summary, the methods described herein can be extended to realize the large-scale production of sandwich-structured films.