Herein, a chemo-mechanical coupled constitutive and failure model is proposed to predict the tensile behavior of SiC/SiC composites under oxidizing environments. The diffusion of O2 through the oxide scale, and the oxidation reaction of SiC/O2 are modeled and implemented in finite element software, through a user-defined element. Numerical validation studies and tests are conducted on a domestic SiC fiber. An orthotropic constitutive model for reinforcements which considers modulus reduction due to oxidation damage, and a continuum damage model associated with O2 diffusion along the micro-cracks in the SiC matrix are subsequently presented. The developed framework is used to simulate the mechanical behavior and oxidation process of a single fiber SiC/SiC composite. This article is protected by copyright. All rights reserved