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Porous CoNiOOH nanosheets derived from the well-mixed MOFs as stable and highly efficient electrocatalysts for water oxidation

催化作用 化学工程 材料科学 分解水 多孔性 纳米技术 化学 复合材料 光催化 有机化学 工程类
作者
Tao Zhao,Dazhong Zhong,Genyan Hao,Guang Liu,Jinping Li,Qiang Zhao
出处
期刊:International Journal of Hydrogen Energy [Elsevier BV]
卷期号:47 (77): 32928-32939 被引量:9
标识
DOI:10.1016/j.ijhydene.2022.07.182
摘要

The development of efficient and stable electrocatalysts is of great significance for improving water splitting. Among them, transition metal oxyhydroxides show excellent performance in oxygen evolution reactions (OER), but there are certain difficulties in direct preparation. Recently, Metal–organic frameworks (MOFs) as precatalysts or precursors have shown promising catalytic performance in OER and can be decomposed under alkaline conditions. Therefore, using a mild and controllable way to convert MOFs into oxyhydroxides and retaining the original structural advantages is crucial for improving the catalytic activity. Herein, a rapid electrochemical strategy is used to activate well-mixed MOFs to prepare Co/Ni oxyhydroxide nanosheets for efficient OER catalysts, and the structural transformation in this process was investigated in detail by using scanning electron microscope, X-ray diffraction, Raman, X-ray photoelectron spectroscopy and electrochemical methods. It is discovered that electrochemical activation can promote ligand substitution of well-mixed MOFs to form porous oxyhydroxide nanosheets and tune the electronic structure of the metal (Co and Ni), which can lead to more active site exposure and accelerate charge transfer. In addition, the change of structure also improves hydrophilicity, as well as benefiting from the strong synergistic effect between multiple species, the optimal a-MCoNi–MOF/NF has excellent OER performance and long-term stability. More obviously, the porous CoNiOOH nanosheets are formed in situ during electrochemical activation process through structural transformation and acts as the active centers. This work provides new insights for mild synthesis of MOFs derivatives and also provides ideas for the preparation of highly efficient catalysts. • CoNiOOH nanosheets derived from the well-mixed MOFs by electrochemical activation. • Porous CoNiOOH species can directly act as real active center for water oxidation. • Porous structures and hydrophilic oxyhydroxide nanosheets play a key role in OER. • The optimal a-MCoNi–MOF/NF exhibits 227 mV overpotential and long-term stability.
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