Enhanced removal of organophosphate esters by iron-modified biochar with developed mesoporous: Performance and mechanism based on site energy distribution theory

Removing the widely concerned pollutant of organophosphate esters (OPEs) by agriculture waste biochar is an effective way to address the waste and pollutant problem simultaneously. In this work, an iron-modified coconut shell biochar (MCSB) was prepared by co-pyrolysis method and used to adsorb tris(2-chloroethyl) phosphate (TCEP) and tris(1-chloro-2-propyl) phosphate (TCPP), which were two typical OPEs. The attention was focused on comprehensively investigating the adsorption behaviors to study the adsorption mechanisms of TCEP and TCPP onto MCSB. With the development of mesoporous and formation of γ-Fe2O3 in MCSB, the adsorption equilibrium was quickly reached in 60 min with the Langmuir maximum adsorption capacities of 211.3 mg/g for TCEP and 223.7 mg/g for TCPP, respectively. Results of adsorption kinetics and isotherm showed the heterogeneous and multilayer of the adsorption process. Pore-filling interaction, the Lewis acid-base interaction, and the hydrophobic interaction were considered to drive the adsorption. And the site energy distribution theory was introduced to further reveal that the physisorption was the main adsorption mechanism, while the Lewis acid-base interaction was responsible for the differences in adsorption of TCEP and TCPP onto MCSB. Additionally, the excellent adsorption performances of MCSB in various circumstances and fixed-bed column experiments suggested that the MCSB would be a promising adsorbent for OPEs removal.