Use of the Iron Chloride Type of Lewis Acid Catalyst in High Reclaimed Asphalt Pavement Content Asphalt Mixtures

The use of reclaimed asphalt pavement (RAP) as a partial replacement for virgin aggregates and asphalt binders has received considerable attention recently. This approach is one of many promising methods for improving sustainability. However, many state Departments of Transportation are cautious in adopting high RAP content into their designs because of cracking and durability issues resulting from the aged RAP binder. A Lewis acid catalyst has been used to modify the asphalt binder’s chemical composition and disrupt the associated molecules formed in the aged RAP binder. The objective of this study is to assess the effectiveness of the use of a Lewis acid catalyst in improving the cracking resistance of an asphalt mixture containing high RAP contents. A suite of laboratory mechanical tests was performed, namely, the dynamic modulus test for linear viscoelastic properties; the semi-circular bend, Illinois flexible index, ideal cracking tolerance, and simplified viscoelastic continuum damage tests for fracture and fatigue resistance; the loaded wheel tracking test for rutting resistance and moisture susceptibility; indirect tensile creep compliance and strength tests for low-temperature cracking resistance; and the Cantabro abrasion test for durability. Further, AASHTOWare Pavement ME software was used to predict the long-term performance of asphalt pavements containing mixtures with high RAP contents and a Lewis acid catalyst. Results showed that the use of the Lewis acid catalyst can disrupt associated molecules formed in the aged RAP binder. Thus, asphalt mixtures containing high RAP contents (recycled binder ratio > 0.20) and a Lewis acid catalyst exhibited similar performances to conventional mixtures. Further, Pavement ME predicted fatigue cracking was lower for a structure containing a FeCl 3 -modified mixture as compared to a similar one with no FeCl 3 , illustrating the effectiveness of FeCl 3 .