废止
芳构化
催化作用
组合化学
化学
铑
基质(水族馆)
相容性(地球化学)
立体化学
有机化学
化学工程
工程类
海洋学
地质学
作者
Lei Gao,Min Wang,Hongwei Ren,Jinzhong Yao,Maozhong Miao,Hongwei Zhou
标识
DOI:10.1021/acs.joc.4c01956
摘要
An efficient method for construction of various fluorenones has been achieved via Rh(III)-catalyzed C–H activation/[4 + 2] annulation/aromatization sequences of simple and readily available enaminones and 1,3-dienes. This protocol showed good substrate compatibility as an array of structurally and electronically diverse fluorenones prepared efficiently in moderate to good yields and preparative scale utility showing very good efficiency in the late-stage functionalization of complex valuable molecules.
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