Atomically Dispersed Metal–Nitrogen–Carbon Catalysts for Acidic Oxygen Reduction Reaction

Designing efficient and cost-effective electrocatalysts toward oxygen reduction reaction (ORR) under demanding acidic environments plays a critical role in advancing proton exchange membrane fuel cells (PEMFCs). Metal–nitrogen–carbon (M–N–C) catalysts with atomically dispersed metals have gained attention for their affordability, excellent catalytic performance, and distinctive features including consistent active sites and high atomic utilization. Over the past decade, significant achievements have been made in this field. This review offers a comprehensive summary of the latest developments in atomically dispersed M–N–C catalysts for ORR in acidic environments along with their applications in PEMFCs. The ORR mechanisms, PEMFC configuration, and operational principles are presented first, followed by an in-depth discussion of strategies to improve the activity and stability of the PEMFC using atomically dispersed M–N–C catalysts at the cathode. Lastly, this review highlights the unresolved challenges and proposes future research pathways for advancing high-performance atomically dispersed M–N–C catalysts and PEMFCs.