Polymeric Charge‐Transporting Materials for Inverted Perovskite Solar Cells

Abstract Inverted perovskite solar cells (PSCs) hold exceptional promise as next‐generation photovoltaic technology, where both perovskite absorbers and charge‐transporting materials (CTMs) play critical roles in cell performance. In recent years, polymeric CTMs have played an important role in developing efficient, stable, and large‐area inverted PSCs due to their unique properties of high conductivity, tunable structures, and mechanical flexibility. This review provides a comprehensive overview of polymeric CTMs used in inverted PSCs, encompassing polymeric hole transport materials (HTMs) and electron transport materials (ETMs). the relationship between their molecular structures, modification strategies are systematically summarized and analyzed for adjusting energy levels, and improving charge extraction, enabling a deep understanding of these widely used materials. The review also explores effective strategies for designing even more efficient polymeric CTMs. Finally, an outlook is proposed on the exciting research of novel polymeric CTMs, paving the way for their commercialized applications in PSCs.