This chapter offers a comprehensive analysis of corrosion inhibitors, focusing on their essential role in protective coatings and their encapsulation within nanocontainers. The discussion delves into the intricate effects of external stimuli on the release behavior of these inhibitors. Initially, the chapter highlights the importance of corrosion inhibitors in coatings and subsequently explores the contemporary delivery approach using nanocontainers. The core of the chapter delves into the diverse effects of different types of stimuli on the release behavior of corrosion inhibitors from nanocontainers. It examines how factors like solution pH, temperature, and concentration influence the controlled release of the encapsulated corrosion inhibitors. Finally, the chapter concludes by addressing current challenges and potential future research directions in this field. This in-depth examination holds significant value for both academic researchers and industrial practitioners, as it contributes to the ongoing advancement of corrosion science. The measurements of self-releasing corrosion inhibitors in response to various stimuli open new possibilities for improving corrosion protection strategies in diverse applications.