羧化
化学
碳负离子
电化学
醌
组合化学
有机化学
催化作用
电极
物理化学
作者
Lin‐Hai Jing,Haiqiong Li,Fenfen Xie,Wenhua Lu,Zhengbing Zhang,Lin‐Hai Jing,Pan Han
标识
DOI:10.1002/adsc.202300789
摘要
Abstract Herein, electrochemical reductive carboxylation of para ‐quinone methides with CO 2 was developed. A variety of value‐added carboxylic acids can be accessed in moderate to excellent yields. Preliminary studies showed that para ‐quinone methides were reduced to benzyl carbanion during the reaction. This protocol features high atom economy, operational simplicity, and environmental friendliness, enabling the synthesis of various carboxylic compounds.
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