Three‐dimensional porous magnetic polyaniline supported Ag nanoparticles nanocomposites as an efficient and recyclable catalyst for nitrophenol reduction

材料科学 聚苯胺 催化作用 纳米复合材料 化学工程 多孔性 纳米颗粒 掺杂剂 纳米技术 兴奋剂 复合材料 有机化学 聚合物 化学 光电子学 工程类 聚合
作者
Huabo Huang,Cheng Li,Naiqing Zhang,Juan Huang,Jiayou Ji,Yulan Liu,Li Liang
出处
期刊:Polymer Composites [Wiley]
卷期号:44 (11): 7674-7686 被引量:5
标识
DOI:10.1002/pc.27655
摘要

Abstract Ag nanoparticles (Ag NPs) nanocomposites are promising catalysts for nitro compound reduction, but simultaneously meeting the requirements of high catalytic activity, stability, recyclability and facile preparation is highly difficult. Herein, the three‐dimensional (3D) porous magnetic polyaniline (PANI) was synthesized using phytic acid (PA) as the dopant/crosslinker, and a recyclable PANI/Ag NPs nanocomposite (PMPA) was obtained through the in situ redox between PANI and AgNO 3 . Characterization results demonstrate that PMPA exhibits a typical 3D porous structure constructed by coral‐like PANI framework with well‐dispersed Ag NPs (10–20 nm) firmly anchored. The PMPA can efficiently catalyze the 4‐nitrophenol (4‐NP) reduction, with a reaction rate constant of 9.5 × 10 −3 s −1 (and 1067.4 s −1 g −1 ), which is highly competitive to the previously reported high‐performance Ag NPs catalysts. This is probably due to the favorable mass/electron conduction of 3D porous structure and strong interaction between PA and Ag. Moreover, the magnetism renders PMPA recyclability via a simple magnetic attraction, and the reaction rate constant remains at a high level after six reuse cycles, up to 4.8 × 10 −3 s −1 . This work highlights the important role of 3D porous PANI in structure of Ag NPs nanocomposites, and paves a new way to develop recyclable catalysts with facile preparation and high catalytic performance. Highlights Facile synthesis via in situ reaction between 3D porous PANI and AgNO 3. Stable dispersion and strong anchor attributed to phytic acid. Conductive porous structure to facilitate mass/electron transportation. Outstanding catalytic performance for 4‐NP reduction and recycle by magnetism.
最长约 10秒,即可获得该文献文件

科研通智能强力驱动
Strongly Powered by AbleSci AI
更新
大幅提高文件上传限制,最高150M (2024-4-1)

科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
Owen应助晴天采纳,获得10
刚刚
Chochee完成签到,获得积分10
刚刚
土豆晴发布了新的文献求助10
1秒前
hesongwen发布了新的文献求助10
2秒前
2秒前
雨渐渐完成签到,获得积分10
3秒前
苔原猫咪甜甜圈完成签到,获得积分10
3秒前
4秒前
啦啦发布了新的文献求助10
5秒前
huang完成签到,获得积分10
5秒前
请叫我湿人人完成签到,获得积分10
5秒前
wuluao0915发布了新的文献求助10
6秒前
赘婿应助清晨五点的沙滩采纳,获得10
6秒前
研友_VZG7GZ应助Aqua采纳,获得10
6秒前
平常的青荷完成签到,获得积分10
7秒前
大个应助科研通管家采纳,获得10
7秒前
爆米花应助科研通管家采纳,获得10
7秒前
Hello应助科研通管家采纳,获得10
7秒前
脑洞疼应助科研通管家采纳,获得10
8秒前
CodeCraft应助科研通管家采纳,获得10
8秒前
8秒前
完美世界应助科研通管家采纳,获得10
8秒前
NexusExplorer应助科研通管家采纳,获得10
8秒前
华仔应助科研通管家采纳,获得10
8秒前
酷波er应助科研通管家采纳,获得10
8秒前
刘叶刀完成签到,获得积分10
8秒前
深情安青应助科研通管家采纳,获得10
8秒前
走走应助科研通管家采纳,获得10
8秒前
9秒前
9秒前
科研通AI2S应助科研通管家采纳,获得10
9秒前
Follow发布了新的文献求助10
9秒前
10秒前
11秒前
科目三应助馒头采纳,获得10
11秒前
王阳洋应助emma采纳,获得10
12秒前
哎呀我去发布了新的文献求助10
12秒前
12秒前
传奇3应助满意沧海采纳,获得10
13秒前
搜集达人应助艺成成采纳,获得10
13秒前
高分求助中
The late Devonian Standard Conodont Zonation 2000
Nickel superalloy market size, share, growth, trends, and forecast 2023-2030 2000
The Lali Section: An Excellent Reference Section for Upper - Devonian in South China 1500
Smart but Scattered: The Revolutionary Executive Skills Approach to Helping Kids Reach Their Potential (第二版) 1000
Very-high-order BVD Schemes Using β-variable THINC Method 850
Mantiden: Faszinierende Lauerjäger Faszinierende Lauerjäger 800
PraxisRatgeber: Mantiden: Faszinierende Lauerjäger 800
热门求助领域 (近24小时)
化学 医学 生物 材料科学 工程类 有机化学 生物化学 物理 内科学 纳米技术 计算机科学 化学工程 复合材料 基因 遗传学 催化作用 物理化学 免疫学 量子力学 细胞生物学
热门帖子
关注 科研通微信公众号,转发送积分 3252159
求助须知:如何正确求助?哪些是违规求助? 2894970
关于积分的说明 8284470
捐赠科研通 2563627
什么是DOI,文献DOI怎么找? 1391819
科研通“疑难数据库(出版商)”最低求助积分说明 651926
邀请新用户注册赠送积分活动 629033