Multifunctional carbon nanotubes-based hybrid aerogels with high-efficiency electromagnetic wave absorption at elevated temperature

In the complex engineering applications of electromagnetic (EM) wave-absorbing materials, it is insufficient for these materials to exhibit only efficient EM wave attenuation ability. EM wave-absorbing materials featuring numerous multifunctional properties are increasingly attractive for next-generation wireless communication and smart devices. Herein, we constructed a lightweight and robust multifunctional hybrid aerogel consisting of carbon nanotubes/aramid nanofibers/polyimide with low shrinkage and high porosity. The hybrid aerogels exhibit excellent EM wave attenuation, with an effective absorption bandwidth covering the entire X-band from 25 °C to 400 °C. The conductive loss capacity of the hybrid aerogel is enhanced under thermal drive, which results in an enhanced ability to attenuate EM waves, as evidenced by the fact that the best-fit thickness drops from 5.3 to 3.6 mm with increasing temperature. In addition, the hybrid aerogels are capable to efficiently absorb sound waves, with an average absorption coefficient as high as 0.86 at 1–6.3 kHz, and they exhibit superior thermal insulation properties, with a thermal conductivity as low as 41 ± 2 mW/mK. They are thus suitable for applications in the anti-icing and infrared stealth fields. The prepared multifunctional aerogels have considerable potential for EM protection, noise reduction, and thermal insulation in harsh thermal environments.