Converting CO2 into Value‐Added Products by Cu2O‐Based Catalysts: From Photocatalysis, Electrocatalysis to Photoelectrocatalysis

Converting CO₂ into value-added products by photocatalysis, electrocatalysis, and photoelectrocatalysis is a promising method to alleviate the global environmental problems and energy crisis. Among the semiconductor materials applied in CO₂ catalytic reduction, Cu₂ O has the advantages of abundant reserves, low price and environmental friendliness. Moreover, Cu₂ O has unique adsorption and activation properties for CO₂ , which is conducive to the generation of C₂₊ products through CC coupling. This review introduces the basic principles of CO₂ reduction and summarizes the pathways for the generation of C₁ , C₂ , and C₂₊ products. The factors affecting CO₂ reduction performance are further discussed from the perspective of the reaction environment, medium, and novel reactor design. Then, the properties of Cu₂ O-based catalysts in CO₂ reduction are summarized and several optimization strategies to enhance their stability and redox capacity are discussed. Subsequently, the application of Cu₂ O-based catalysts in photocatalytic, electrocatalytic, and photoelectrocatalytic CO₂ reduction is described. Finally, the opportunities, challenges and several research directions of Cu₂ O-based catalysts in the field of CO₂ catalytic reduction are presented, which is guidance for its wide application in the energy and environmental fields is provided.