High Mobility Ambipolar Diketopyrrolopyrrole‐Based Conjugated Polymer Synthesized Via Direct Arylation Polycondensation

A diketopyrrolopyrrole-based conjugated polymer, PDPP-4FTVT, which exhibits ambipolar transport behavior in air with hole and electron mobilities up to 3.40 and 5.86 cm2 V−1 s−1, respectively, is synthesized via direct arylation polycondensation. Incorporation of F-atoms in β-positions of thiophene rings dramatically improves the efficiency of direct arylation polycondensation. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.