Precipitation behavior, density, viscosity, and CO2 absorption capacity of highly concentrated ternary AMP-PZ-MEA solvents

溶剂 降水 化学 三元运算 胺气处理 粘度 吸收(声学) 分析化学(期刊) 核化学 色谱法 材料科学 有机化学 物理 气象学 复合材料 程序设计语言 计算机科学
作者
Rattanaporn Apaiyakul,Prathana Nimmanterdwong,Thitiya Kanchanakungvalkul,Papitchaya Puapan,Hongxia Gao,Zhiwu Liang,Paitoon Tontiwachwuthikul,Teerawat Sema
出处
期刊:International Journal of Greenhouse Gas Control [Elsevier BV]
卷期号:120: 103775-103775 被引量:16
标识
DOI:10.1016/j.ijggc.2022.103775
摘要

This study explored potential of highly concentrated AMP-PZ-MEA solvent for capturing CO2 in terms of solvent precipitation, density, viscosity, and CO2 absorption capacity. It was found that most of the studied AMP-PZ-MEA solvents precipitated at high AMP and PZ concentrations and at high CO2 loading. The minimum possible MEA concentration (which can maintain a clear solvent) was 1.5 M for 6 M total amine concentration. It was also observed that an increase of AMP and/or PZ concentration in the 6 M blends induced the solvent precipitation. MEA was the only amine component that can be added to the blends to elevate the total amine concentration from 6 M to 7 M. As a result, the six AMP-PZ-MEA blends were suggested: 2:2.5:1.5, 1.3:3.2:1.5, 0.95:3.55:1.5 (for 6 M) and 2:2.5:2.5, 1.3:3.2:2.5, and 0.95:3.55:2.5 (for 7 M). The proposed blends are corresponding to PZ:AMP molar ratio of 1.25, 2.5, and 3.75, which are much higher than that of the first-generation AMP-PZ-MEA solvents. Regarding the visualized observation, there was no solid sediments observed throughout precipitation and CO2 absorption studies of the six blends. Interestingly, densities of the proposed blends were close to that of 5 M MEA, while their viscosities were much higher than that of 5 M MEA but were close to that of MDEA-PZ and AMP-PZ. Additionally, CO2 absorption capacities of the proposed 6 M and 7 M blends were 56-58% and 64-71% higher than that of 5 M MEA. These numbers are much higher than those of the first-generation AMP-PZ-MEA solvents.
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