Sulfur-functionalized biochar: Synthesis, characterization, and utilization for contaminated soil and water remediation-a review

The development of innovative, eco-friendly, and cost-effective adsorbents is crucial for addressing the widespread issue of organic and inorganic pollutants in soil and water. Recent advancements in sulfur reagents-based materials, such as FeS, MoS₂, MnS, S⁰, CS₂, Na₂S, Na₂S₂O₃^2-, H₂S, S-nZVI, and sulfidated Fe⁰, have shown potential in enhancing the functional properties and elemental composition of biochar for pollutant removal. This review explores the synthesis and characterization of sulfur reagents/species functionalized biochar (S-biochar), focusing on factors like waste biomass attributes, pyrolysis conditions, reagent adjustments, and experimental parameters. S-biochar is enriched with unique sulfur functional groups (e.g., C-S, -C-S-C, C=S, thiophene, sulfone, sulfate, sulfide, sulfite, elemental S) and various active sites (Fe, Mn, Mo, C, OH, H), which significantly enhance its adsorption efficiency for both organic pollutants (e.g., dyes, antibiotics) and inorganic pollutants (e.g., metal and metalloid ions). The literature analysis reveals that the choice of feedstock, influenced by its lignocellulosic content and xylem structure, critically impacts the effectiveness of pollutant removal in soil and water. Pyrolysis parameters, including temperature (200-600 °C), duration (2-10 h), carbon-to-hydrogen (C:H) and oxygen-to-hydrogen (O:H) ratios in biochar, as well as the biochar-to-sulfur reagent modification ratio, play key roles in determining adsorption performance. Additionally, solution pH (2-8) and temperature (288, 298, and 308 K) affect the efficiency of pollutant removal, though optimal dosages for adsorbents remain inconsistent. The primary removal mechanisms involve physisorption and chemisorption, encompassing adsorption, reduction, degradation, surface complexation, ion exchange, electrostatic interactions, π-π interactions, and hydrogen bonding. This review highlights the need for further research to optimize synthesis protocols and to better understand the long-term stability and optimal dosage of S-biochar for practical environmental applications.