Recent progress of sub-1 nm nanomaterials: synthesis, polymer-analogue properties and applications in redox catalysis

Sub-1 nm nanomaterials (SNMs) have attracted attention for their novel structures and size-related properties. In the past decade, various SNMs were synthesized, such as nanowires, nanorings, nanosheets, nanobelts, nanotubes, and other superstructures. We discussed their synthetic strategies systematically, including the ligand pathway and the cluster-nuclei co-assembly pathway. In addition, SNMs exhibit unique size-related properties. Firstly, SNWs show polymer-analogue properties due to their sub-nanometric size and ultrahigh aspect ratio. We illustrate the polymer-analogue properties on both microscopic and macroscopic scales. The macroscopic assemblies of SNWs can be widely applied for organic liquid storage, energy, and optical applications. Finally, we summarized the applications of SNMs in redox catalysis. Their extraordinary catalytic activity is attributed to their large specific surface area and electronic delocalization at the sub-nanometric scale. We hope this feature article can provide new viewpoints on the design and applications of SNMs.