膜
普鲁士蓝
催化作用
材料科学
润湿
降级(电信)
化学工程
污染物
纳米技术
化学
复合材料
有机化学
电极
物理化学
工程类
电信
生物化学
电化学
计算机科学
作者
Jiaxin Li,Huiyu Yi,Xiao Yang,Chenge Liang,Yi Shen,Yungui Li,Qile Fang
标识
DOI:10.1016/j.apcatb.2023.122922
摘要
Membrane catalysis is a frontier technology for effectively removing organic containments, and burgeoning membranes assembled from two-dimensional (2D) materials have significantly flourished in peroxymonosulfate (PMS)-based catalytic membrane processes. Here, a bottom-up strategy based on restricting CoFe Prussian blue analog (PBA) crystal growth in one direction is used to fabricate large-scale 2D blade-shaped PBA sheets, whose radial size and thickness can be adjusted by the precursor ion ratio (CoII/FeII). The stripe CoFe PBA sheets can directly serve as building blocks and are simply assembled into a free-standing 2D membrane by interweaving assembly. The assembled CoFe PBA catalytic membrane possesses excellent wetting properties, guaranteeing an unimpeded mass transfer process, which leads to a superior instantaneous catalytic performance for the antibiotic norfloxacin during the continuous and flow-through membrane catalytic process. SO4•− and 1O2 are demonstrated to be the main active species, which synergistically contribute to the PMS-driven organic degradation.
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