过电位
塔菲尔方程
析氧
催化作用
材料科学
电化学
电导率
电流密度
化学工程
电催化剂
电阻率和电导率
无机化学
物理化学
电极
化学
有机化学
电气工程
工程类
物理
量子力学
作者
Qichen Liang,Nana Du,Huajie Xu
标识
DOI:10.1142/s1793604723400337
摘要
The development of cheap, high activity and stability catalysts for oxygen evolution reaction (OER) is of great significance because of its important role in energy storage technology. Herein, flower-like CoSe 2 -Co 3 O 4 -Ag with enhanced electrochemical performance was synthesized by simple methods. The CoSe 2 -Co 3 O 4 -Ag exhibits lower overpotential and higher current density, with an overpotential of 324 mV at the current density of 10 mA⋅cm[Formula: see text] and a Tafel slope of 65.69 mA⋅dec[Formula: see text]. From the ECSA normalized LSV curves, higher electrocatalytic activity for OER is mainly due to the increase of ESCA and conductivity, minor due to adjusting the electronic configuration. These strategies to improve electrochemical active area and conductivity have valuable reference for designing cheap, high activity and stability catalysts.
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