A Thermo‐Responsive MOFs for X‐Ray Scintillator

Thermo-responsive smart materials have aroused extensive interest due to the particular significance of temperature sensing. Although various photoluminescent materials are explored in thermal detection, it is not applicable enough in X-ray radiation environment where the accuracy and reliability will be influenced. Here, a strategy is proposed by introducing the concept of radio-luminescent functional building units (RBUs) to construct thermo-responsive lanthanide metal-organic frameworks (Ln-MOFs) scintillators for self-calibrating thermometry. The rational designs of RBUs (including organic ligand and Tb³⁺/Eu³⁺) with appropriate energy levels lead to high-performance radio-luminescence. Ln-MOFs scintillators exhibit perfect linear response to X-ray, presenting low dose rate detection limit (min ≈156.1 nGy_airs^-1). Self-calibrating detection based on ratiometric XEL intensities is achieved with good absolute and relative sensitivities of 6.74 and 8.1%K^-1, respectively. High relative light yield (max ≈39000 photons MeV^-1), imaging spatial resolution (max ≈18 lp mm^-1), irradiation stability (intensity ≈100% at 368 K in total dose up to 215 Gy_air), and giant color transformation visualization benefit the applications, especially the in situ thermo-responsive X-ray imaging. Such strategy provides a promising way to develop the novel smart photonic materials with excellent scintillator performances.