超级电容器
聚苯胺
热解炭
材料科学
炭黑
阳极
碳纤维
储能
电化学
阴极
化学工程
聚合
纳米技术
电容
复合材料
复合数
化学
物理化学
电极
热解
工程类
聚合物
物理
功率(物理)
天然橡胶
量子力学
作者
Guosai Jiang,Meiling Chen,Yanzhi Sun,Junqing Pan
标识
DOI:10.1016/j.est.2023.106955
摘要
In view of massive accumulation of pyrolytic carbon black (CBp) from waste tires with low quality, it is urgent to explore its application in electrochemical energy storage to realize the high-value utilization of carbon resources and reduce the cost of supercapacitors. Herein, in-situ polymerization of aniline monomers on activated CBp (ACBp) with the introduction of o-phenylenediamine (OPD) for enhanced N content was first performed to prepare the composite of CBp and polyaniline (PANI), denoted as ACBp-oPANI, and then a dual N-doped material (ACBp-oN) was obtained via direct activation of ACBp-oPANI. The ACBp-oN product shows satisfactory specific capacitance of 335 F g−1 (1 A g−1) with superior rate performance as well as long cycle life in three-electrode system. The investigated charging/discharging kinetics reveal rapid electron transport and ion diffusion, which are attributed to its doped N and enriched channel structure. Besides, the assembled Zn ion hybrid supercapacitor (Zn|C), including ACBp-oN cathode and electrodeposited Zn anode, delivers an amazing energy density of 68.9 Wh kg−1 which is almost 4 times higher than that of conventional symmetrical supercapacitor (C|C), demonstrating more practicality. The research provides new perception into the high-value utilization of waste CBp resources in energy field and strategy for the boosted electrochemical properties of carbon-based materials via the suggested Zn|C energy storage system.
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