Highly Efficient Inherent Linearly Polarized Electroluminescence from Small‐Molecule Organic Single Crystals

Abstract Small‐molecule organic single crystals (SCs) with an inherent in‐plane anisotropic nature enable direct linearly polarized light emission without the need for spatially separated polarizers and complex optical structures. However, the device performance is severely restricted by the starvation of appropriate SC emitters and the difficulty in the construction of efficient SC electroluminescence (EL) devices, leading to a low external quantum efficiency (EQE) of usually smaller than 1.5%. Here, highly efficient inherent linearly polarized light‐emitting diodes (LP‐LEDs) are demonstrated by exploiting 2,6‐diphenylanthracene (DPA) SCs as intrinsically polarized emitters. The LP‐LEDs exhibit a 2.5‐fold enhanced maximum EQE of 3.38%, which approaches the theoretical limit for the DPA SC‐based EL device and is the highest among organic SC‐based LEDs reported thus far. More importantly, a high degree of polarization (DOP) up to 0.74 is achieved for the intrinsically polarized EL emission of the DPA SC‐based LP‐LEDs. By leveraging the highly efficient LP‐LED, an interchip polarized optical communication system consisting of organic SCs is demonstrated for the first time. This work creates a solid foundation for the exploitation of a vast new library of small‐molecule organic SCs for LP‐LEDs and carries broad implications for polarized optics and relevant optoelectronic devices.