光催化
异质结
可见光谱
降级(电信)
材料科学
化学工程
碲化镉光电
半导体
光化学
光电子学
化学
计算机科学
催化作用
有机化学
电信
工程类
作者
Yinyan Gong,Yujie Wu,Xu Yan,Lei Li,Can Li,Xinjuan Liu,Lengyuan Niu
标识
DOI:10.1016/j.cej.2018.05.186
摘要
Due to their high persistence and ecotoxicity, developing a green and efficient approach to remove antibiotic residuals from aquatic environments becomes a challenging task. Efficient, visible light-active and reusable semiconductor photocatalyst is a promising solution to address this issue. In this work, Z-scheme CdTe/TiO2 heterostructure photocatalysts were prepared by a hydrothermal method and the photocatalytic performance of as-prepared samples was evaluated by degradation of tetracycline hydrochloride (TC-H) under visible-light irradiation. The optimal performance was achieved for CdTe/TiO2 heterostructure photocatalyst grown at 120 °C, which can decompose 78% TC-H after 30 min irradiation. The improved photocatalytic performance can be ascribed to synergistic effects including excellent visible-light absorption, efficient charge separation and relatively high redox potentials of electrons and holes associated with Z-scheme charge transfer mechanism. The possible degradation byproducts and stability of CdTe/TiO2 heterostructures for TC-H degradation are also elucidated. This Z-scheme CdTe/TiO2 photocatalysts may present a new strategy for degradation of antibiotics, providing an invaluable methodology for alleviation of aquatic environment pollution.
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