纳米晶
动力学
电化学
二氧化钛
材料科学
化学工程
磷
化学
纳米技术
电极
物理化学
复合材料
冶金
量子力学
物理
工程类
作者
Qingbing Xia,Yang Huang,Jin Xiao,Lei Wang,Zeheng Lin,Weijie Li,Hui Liu,Qinfen Gu,Huan Liu,Shulei Chou
标识
DOI:10.1002/anie.201813721
摘要
Structural modulation and surface engineering have remarkable advantages for fast and efficient charge storage. Herein, we present a phosphorus modulation strategy which simultaneously realizes surface structural disorder with interior atomic-level P-doping to boost the Na+ storage kinetics of TiO2 . It is found that the P-modulated TiO2 nanocrystals exhibit a favourable electronic structure, and enhanced structural stability, Na+ transfer kinetics, as well as surface electrochemical reactivity, resulting in a genuine zero-strain characteristic with only approximately 0.1 % volume variation during Na+ insertion/extraction, and exceptional Na+ storage performance including an ultrahigh rate capability of 210 mAh g-1 at 50 C and a strong long-term cycling stability without significant capacity decay up to 5000 cycles at 30 C.
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