Interaction behaviors of Cr(VI) at biotite-water interface in the presence of HA: Batch, XRD and XPS investigations

The interaction behaviors of heavy metals and micaceous minerals are extremely important to understand the environmental behaviors of heavy metals. In this work, the interaction behaviors of Cr(VI) and biotite in the presence and absence of HA were studied combining batch and spectroscopic approaches. Batch experiments showed that biotite had the ability to remove Cr(VI) from the water and the removal markedly increased with decreasing pH. However, sorption of total Cr onto biotite increased with increasing pH (2.0–4.0), whilst quickly decreased above pH ∼ 4.0. It was worth noting that redox process of Cr(VI) to Cr(III), caused by structural Fe(II) on biotite, was another important factor for the high removal of Cr(VI) in a pH range of 2.0–4.0. Ionic strength also influenced Cr(VI) removal that Cr(VI) removal became higher with increasing ion strength. The presence of HA did not show obvious macroscopic effect on Cr(VI) removal, however, HA could cover biotite surface, and promote the sorption of total Cr onto biotite and attenuate the reduction effect caused by Fe(II) on biotite. Spectroscopic approaches, like FT-IR, XRD and XPS further confirmed the existence of Cr(III) on biotite interacting with Cr(VI) and the reduction of Cr(VI) to Cr(III) was drove by the Fe(II) dissolving from biotite to Fe(III). Further, sorption effect and reduction effect competitively contributed to the Cr(VI) removal by biotite, and reduction effect played a more important role at lower pH. • Biotite removed Cr(VI) from 0% to 100% with pH decreasing from 7.0 to 2.0. • Sorption of total Cr on biotite acted more around pH 4.0. • Cr(VI) reduction caused by structure Fe(II) in biotite increased with the pH decreasing from 4.0 to 2.0. • The presence of HA accelerated Cr(VI) adsorption and attenuated reduction effect.