催化作用
双金属片
苯
环己烷
甲苯
沸石咪唑盐骨架
路易斯酸
无机化学
咪唑酯
热解
化学工程
化学
材料科学
吸附
有机化学
金属有机骨架
工程类
作者
Yunlong Guo,Meicheng Wen,Shengnan Song,Qiuxia Liu,Guiying Li,Taicheng An
标识
DOI:10.1016/j.apcatb.2022.121212
摘要
In this work, ZnCoOx catalysts were prepared using in situ pyrolysis of ZnCo bimetallic zeolitic imidazolate frameworks (ZIFs), which were rationally designed on the basis of a metal ion doping strategy. The derived Zn0.05CoOx with proper doping of Zn (Zn/Co molar ratio of 0.05) exhibited superior catalytic activity and durability towards catalytic elimination of different volatile organic compounds (VOCs) including benzene, toluene and cyclohexane under simulated real-exhaust conditions. Both Brønsted and Lewis acid sites were beneficial for cyclohexane degradation, whereas only Lewis acid sites were responsible for eliminations of benzene and toluene. In addition, the effect of chemical structures of VOCs on their catalytic elimination over Zn0.05CoOx was explored. Compared to benzene and toluene, cyclohexane molecule was more easily eliminated, attributed to strong adsorption onto catalyst and special chemical structure of cyclohexane. The obtained results can provide new strategy for rational design of highly efficient catalytic materials for eliminating VOCs.
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