One‐Step MOF‐Templated Strategy to Fabrication of Ce‐Doped ZnIn2S4 Tetrakaidecahedron Hollow Nanocages as an Efficient Photocatalyst for Hydrogen Evolution

Achieving structure optimizing and component regulation simultaneously in the ZnIn₂ S₄ -based photocatalytic system is an enormous challenge in improving its hydrogen evolution performance. 3D hollow-structured photocatalysts have been intensively studied due to their obvious advantages in solar energy conversion reactions. The synthesis of 3D hollow-structured ZnIn₂ S₄ , however, is limited by the lack of suitable template or synthesis methods, thereby restricting the wide application of ZnIn₂ S₄ in the field of photocatalysis. Herein, Ce-doped ZnIn₂ S₄ photocatalysts with hollow nanocages are obtained via one-step hydrothermal method with an ordered large-pore tetrakaidecahedron cerium-based metal-organic frameworks (Ce-MOFs) as template and Ce ion source. The doping of Ce and the formation of ZnIn₂ S₄ tetrakaidecahedron hollow nanocages with ultrathin nanosheet subunits are simultaneously induced by the Ce-MOFs, making this groundbreaking work. The Ce-doped ZnIn₂ S₄ with a nonspherical 3D hollow nanostructure inherit the tetrakaidecahedron shape of the Ce-MOF templates, and the shell is composed of ultrathin nanosheet subunits. Both theoretical and experimental results indicate that the doping of Ce and the formation of hollow nanocages increase light capture and the separation of photogenerated charge carriers.