催化作用
化学
组合化学
纳米技术
材料科学
有机化学
作者
Suhelen Vásquez‐Céspedes,Angélique Ferry,Lisa Candish,Frank Glorius
标识
DOI:10.1002/anie.201411997
摘要
Abstract The first general methodology for the direct thiolation of electron‐rich heteroarenes was developed by employing Pd/Al 2 O 3 , a recoverable and commercially available heterogeneous catalyst, and CuCl 2 . This method represents an operationally simple approach for the synthesis of these valuable compounds. Preliminary mechanistic studies indicate a heterogeneous catalytic system, in which both metals play a complementary role in the formation of the thiolated products.
科研通智能强力驱动
Strongly Powered by AbleSci AI