苯甲醛
苯甲醇
化学
激进的
甲苯
自动氧化
苯甲酸
药物化学
链式传播
光化学
反应性(心理学)
过氧化氢
酒
分子内力
有机化学
催化作用
单体
聚合物
替代医学
病理
医学
作者
Ive Hermans,Jozef Peeters,Luc Vereecken,Pierre Jacobs
出处
期刊:ChemPhysChem
[Wiley]
日期:2007-12-13
卷期号:8 (18): 2678-2688
被引量:56
标识
DOI:10.1002/cphc.200700563
摘要
Abstract Aerobic oxidation of toluene (PhCH 3 ) is investigated by complementary experimental and theoretical methodologies. Whereas the reaction of the chain‐carrying benzylperoxyl radicals with the substrate produces predominantly benzyl hydroperoxide, benzyl alcohol and benzaldehyde originate mainly from subsequent propagation of the hydroperoxide product. Nevertheless, a significant fraction of benzaldehyde is also produced in primary PhCH 3 propagation, presumably via proton rather than hydrogen transfer. An equimolar amount of benzyl alcohol, together with benzoic acid, is additionally produced in the tertiary propagation of PhCHO with benzylperoxyl radicals. The “hot” oxy radicals generated in this step can also abstract aromatic hydrogen atoms from PhCH 3 , and this results in production of cresols, known inhibitors of radical‐chain reactions. The very fast benzyl peroxyl‐initiated co‐oxidation of benzyl alcohol generates HO 2 . radicals, along with benzaldehyde. This reaction also causes a decrease in the overall oxidation rate, due to the fast chain‐terminating reaction of HO 2 . with the benzylperoxyl radicals, which causes a loss of chain carriers. Moreover, due to the fast equilibrium PhCH 2 OOH+HO 2 . ⇌PhCH 2 OO . +H 2 O 2 , and the much lower reactivity of H 2 O 2 compared to PhCH 2 OOH, the fast co‐oxidation of the alcohol means that HO 2 . gradually takes over the role of benzylperoxyl as principal chain carrier. This drastically changes the autoxidation mechanism and, among other things, causes a sharp decrease in the hydroperoxide yield.
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