快离子导体
固态核磁共振
魔角纺纱
锂(药物)
化学
离子
核磁共振波谱
电解质
导电体
化学物理
分析化学(期刊)
核磁共振
材料科学
物理化学
电极
物理
有机化学
医学
内分泌学
复合材料
作者
Yuxuan Xiang,Guorui Zheng,Guiming Zhong,Dawei Wang,Riqiang Fu,Yong Yang
标识
DOI:10.1016/j.ssi.2017.11.025
摘要
Solid state lithium ion conductors are promising to replace the organic liquid electrolytes for a safer and long cycle-life lithium battery. However, solid electrolytes are still not fully explored and need extensive basic studies to understand their intrinsic conducting mechanism and interfacial properties between electrodes and electrolytes. In this review, we highlight the latest progresses in the research of lithium ion conductors by using advanced solid state nuclear magnetic resonance(SS NMR) spectroscopy, i.e. Magic angle spinning (MAS) NMR, pulsed-field gradient (PFG) NMR, spin-lattice(SLR) as well as spin-spin relaxation NMR, spin alignment echo (SAE) NMR and two-dimensional exchange (2D EXSY) NMR, and briefly review the application of these solid NMR techniques in LISICON-, NASICON- and Garnet-type lithium ion conductors in the different time/length scales, as well as the measurement in the determination of ion occupancy, ion diffusion pathways, and diffusion coefficients.
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