Visible-light induced di- and trifluoromethylation of N-benzamides with fluorinated sulfones for the synthesis of CF2H/CF3-containing isoquinolinediones

A photocatalytic radical di- or trifluoromethylation/cyclization of methacryloyl benzamides with fluorinated sulfones provided an efficient route to CF₂H/CF₃-containing isoquinoline-1,3(2H,4H)-diones.