电子顺磁共振
异质结
煅烧
降级(电信)
光催化
反应速率常数
可见光谱
化学
电子转移
核化学
猝灭(荧光)
恩诺沙星
催化作用
材料科学
光化学
环丙沙星
动力学
核磁共振
有机化学
光电子学
荧光
量子力学
物理
生物化学
电信
抗生素
计算机科学
作者
Xiangchen Li,Dan Feng,He Xiaoyan,Dayi Qian,Bate Nasen,Baochuan Qi,Shuwen Fan,Jiangwei Shang,Xiuwen Cheng
标识
DOI:10.1016/j.seppur.2022.122219
摘要
Herein, a series of Z-type heterojunctions Fex[email protected]2-Y were synthesized by a combination of calcination and hydrothermal methods for the removal of ciprofloxacin (CIP) by peroxymonosulfate (PMS) activation under visible light. It was optimized that Fe3[email protected]2-4 exhibited excellent photocatalytic performance, with the degradation rate of CIP 84 % within 140 min. Besides, its rate constants were 23.74, 3.59, and 3.98 times higher than those of pure g-C3N4, Fe3CN, and MoS2, respectively. Furthermore, the Fe3[email protected]2-4/PMS/vis system could efficiently degrade other antibiotics (enrofloxacin (ENRO), metronidazole (MNZ) and tetracycline (TC)). The quenching experiments and electron paramagnetic resonance (EPR) characterization showed that reactive substances such as 1O2, h+ and Ovs played a dominant role in this system. We deeply explore the possible mechanisms and CIP degradation pathways for the enhanced CIP degradation efficiency in the Fe3[email protected]2-4/PMS/vis system. Among them, the exposed Mo (IV) and Fe (II) sites on the catalyst surface accelerated the electron transfer, while the S2- therein promoted the cycling between ions, thus increasing the reaction rate. Finally, Fe3[email protected]2-4 maintained appreciable performance even after 5 cycles. This study may provide a new approach for the development of metal-doped g-C3N4-based complexes.
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