Beyond S and Se: Electrocatalytic Hydrogen Production by Tellurolate-Bridged Co(III)–Mn(I) Heterodinuclear Complexes

In the pursuit of efficient electrocatalysts for the hydrogen evolution reaction (HER), a series of manganese and cobalt heterodinuclear complexes have been synthesized and characterized that have a stark resemblance with the [NiFe]-hydrogenase active site structure. Irradiation of [Mn