Solar Light-Driven Molecular Oxygen Activation by BiOCl Nanosheets: Synergy of Coexposed {001}, {110} Facets and Oxygen Vacancies

Single-crystalline BiOCl nanosheets with coexposed {001} and {110} facets, as well as oxygen vacancies, were synthesized using a simple method. These nanosheets have the ability to activate molecular oxygen, producing reactive superoxide radicals (77.8%) and singlet oxygen (22.2%) when exposed to solar light. The BiOCl demonstrated excellent photocatalytic efficiency in producing H₂O₂ under simulated solar light and in oxidatively hydroxylating phenylboronic acid under blue LED light. Our research highlights the significance of constructing coexposed {001} and {110} facets, as well as oxygen vacancies, in enhancing photocatalytic performance. The BiOCl nanosheets have the capability to produce H₂O₂ with a solar-to-chemical energy conversion efficiency of 0.11%.