Construction of dual driving force in carbon nitride for highly efficient hydrogen evolution: Simultaneously manipulating carriers transport in intra- and interlayer

Photocatalytic hydrogen evolution is widely recognized as an environmentally friendly approach to address future energy crises and environmental issues. However, rapid recombination of photo-induced charges over carbon nitride in lateral and vertical direction hinder this process. Herein, we proposed an effective strategy involving the embedding of benzene rings and the intercalation of platinum atoms on carbon nitride for a controlled intralayer and interlayer charges flow. Modified carbon nitride exhibits a significant higher hydrogen evolution rate (6288.5 μmol/g/h), which is 42 times greater than that of pristine carbon nitride. Both experiments and simulations collectively indicate that the improved photocatalytic activities can be attributed to the adjustment of the highly symmetric structure of carbon nitride, achieved by embedding benzene rings to induce the formation of an intralayer build-in electric field and intercalating Pt atoms to enhance interlayer polarization, which simultaneously accelerate lateral and vertical charges migration. This dual-direction charges separation mechanism in carbon nitride provides valuable insights for the development of highly active photocatalysis.