Enhanced sintering resistance of NiFe‐based RWGS catalysts through Cu doping

Abstract The reverse water‐gas shift (RWGS) reaction offers an effective method for mitigating CO 2 emissions. Due to its affordability and physicochemical stability, iron has garnered significant attention as a potential catalyst for RWGS. The incorporation of nickel and copper promoters can enhance CO 2 conversion and CO selectivity in Fe‐based catalysts. This study focuses on modifying the strength of the Strong Metal‐Support Interaction (SMSI) through particle size optimization. Doping Cu into NiFe‐based catalysts restricts particle size, which influences the curvature of the Ni 0 @FeO x interface. This curvature enhances the electron coupling between Ni 0 and FeO x , promoting the formation of a denser and thicker Ni 0 and FeO x layer. This results in a nearly 90% increase in the CO 2 reaction rate during the sintering resistance test by anchoring Ni 0 and facilitating electron transfer to active sites. Such morphological evolution improves high‐temperature resistance to sintering during RWGS. © 2024 Society of Chemical Industry and John Wiley & Sons, Ltd.