Preparation of excellent performance ZTA ceramics and complex shaped components using digital light processing 3D printing technology

Complex cellular structured Al2O3 ceramics is difficult to fabricate due to its poor toughness. To overcome this limitation, La2O3 and ZrO2 were introduced into Al2O3 ceramics in digital light processing (DLP) 3D printing. The toughening of ZrO2 and in-situ formation of platelet grains by La2O3 addition dramatically increased the performance of printed ceramics (flexural strength of 556.6 MPa, fracture toughness of 6.94 MPa·m1/2, Vickers hardness of 18.88 GPa, and an apparent porosity of 0.09%), which exceeds most of those fabricated by traditional process. Furthermore, four different cellular structures were successfully fabricated with a Diamond-structure being the best (compressive strength of 40.62 MPa, Young's modulus of 2.41 GPa, energy absorption of 0.45 MJ/m3, cellular density of 1.70 g/cm3, and specific strength of 23.83 MPa/(g/cm3)). This study presents a novel strategy for using DLP 3D printing technology in the fabrication of lightweight, high-strength and complex shaped ceramic components. It aims to expedite the rapid application of DLP 3D printing technology in various fields such as aerospace and medical.